Vapor pressure is a pesticide's tendency to "evaporate." In other words, to change from a solid or liquid
into a
vapor.1
In general, pesticides with low vapor
pressures are less likely to turn
into a vapor and get into the air. Those
with high vapor pressures are more likely to get into the air. You'll typically see vapor pressure measured
in
torr or
millimeters of mercury (mmHg) at 25 °C (77 °F). These units describe pressure like "pounds" and
"grams"
describe
weight.
Image: Examples of pesticide vapor pressure.2,3,4,5
(photo credit: National Pesticide Information Center)
How is a pesticide's vapor pressure determined?
If you were to place a pesticide in a container and close it, some of it would stay at the bottom. Some of it
may
also evaporate into the air inside the container. The pressure from these trapped vapors pushing outward can
be
measured. This can be done with pressure gauges or other devices. These measuring devices are able to detect
very low pressures.6
Why is a pesticide's vapor pressure important?
A pesticide's vapor pressure can tell us quite a bit about how it will act inside and outside.
Whether people or animals are at risk of breathing in the pesticide. Pesticides that quickly and
easily turn
into vapors can increase this risk.7
While some pesticides will stay grounded after they are applied, others may be more likely to move up into
the
air.
It is important to know which type
of
pesticide you might be dealing with
before it's used. Pesticides with higher
vapor pressures tend to move into the air faster and easier. This can increase the chance of breathing them
in.
Vapors may more easily reach the skin and eyes. Wind may also carry vapors away to other areas.
If you know the vapor pressure of a pesticide, you can better predict how it will act both indoors and
outdoors.
You can also take steps to lower the risk to
people, animals, and the
environment. For example, a farmer might use
plastic row covers to prevent a highly volatile pesticide from escaping from soil. This helps prevent harm
to
nearby
people, plants, and animals. When using volatile pesticides indoors, professionals might wear respirators
and
other protective equipment. Always check the
pesticide label! It will list
the minimum precautions and protective
equipment that are necessary.
To keep your risk low in your own home, you may
consider:
Covering vents (or other sensitive items) when spraying nearby.
Turning off air circulation to rooms being sprayed.
Using volatile pesticides only in well-ventilated areas.
Avoiding the use of volatile pesticides near exposed food items.
Ventilating the area after application by opening windows and doors and/or using fans.
Keeping people and pets out until the area has been well-ventilated.
Avoiding treated areas until sprays have dried thoroughly.
What can influence a pesticide's vapor pressure in the environment?
Many things can affect whether or not a pesticide will get into the air. In fact, pesticides can have
different
vapor
pressures under different conditions. Temperature plays a very large role here.7
In general, pesticides will have
lower vapor pressures at lower temperatures. As temperature goes up, so does the pesticide's vapor pressure.
Other environmental factors, like climate, soil type, and moisture level can also affect a pesticide's
volatility.
Pesticides can also stick to soil, be broken apart by water and light, and dissolve in water. These things
can
affect
how likely it is to become a vapor. The way a pesticide is applied can also play a role.7 For
example, a pesticide with
small droplets, like an aerosol, may get into the air more easily than a spray with larger droplets.
Additionally, the other
ingredients in a pesticide product
can speed up or slow down
the active ingredient's
transition to the vapor phase.8 A quick example of how
some of these factors work
together can be found in the
following images.
What happens to a pesticide once it becomes a vapor?
In the air, pesticides can break down, be breathed in, and move away from the treated area into new
areas.7
When
pesticides move off-target as vapors, that is known as vapor drift.9
Pesticide
vapors can be broken apart by light,
water, and microbes. They can also stick to dust particles in the air and be carried away by air
currents.
Later, wind
or rain may deposit those airborne pesticides onto soil, water, plants, or animals in other
areas.7
Becoming a vapor isn't the only way that a pesticide can move away from the place it is applied. Dust
particles
or
spray droplets can also move through the air during or shortly after pesticide use. This is known as
particle drift.9,10
Pesticide labels have information about how to reduce the risk of drift. For some products, that might
mean
using
very specific spray nozzles, limiting the release height, or not applying under certain weather
conditions.
Additional
methods can include adding a thickener to the spray tank, reducing the spray pressure, or using spray
shields.11 If
you suspect pesticide drift, contact the pesticide authority
in your
state.
Where can I get more information?
For more detailed information about pesticide vapor pressure please visit the list of referenced
resources
below or call the National Pesticide Information Center, Monday - Friday,
between 8:00am - 12:00pm Pacific Time (11:00am - 3:00pm Eastern Time) at 1-800-858-7378 or visit us
on the web at http://npic.orst.edu.
NPIC
provides objective, science-based
answers to questions about pesticides.
Date Reviewed: May 2016
Please cite as: Hanson, B.; Bond, C.; Buhl, K. 2016. Pesticide Vapor
Pressure Fact Sheet;
National Pesticide Information Center, Oregon State University Extension Services. http://npic.orst.edu/factsheets/vaporpressure.html.
References:
Hornsby, A. G.; Wauchope, R. D.; Herner, A. E. Pesticide Properties: Vapor Pressure. Pesticide
Properties
in the
Environment; Springer-Verlag: New York, 1996; pp 9–10.
Reregistration Eligibility Decision for Permethrin; U.S. Environmental Protection Agency,
Office of
Prevention,
Pesticides and Toxic Substances, Office of Pesticide Programs, Environmental Fate and Effects Division,
U.S.
Government Printing Office: Washington, DC, 2007.
Reregistration Eligibility Science Chapter for Chlorpyrifos Fate and Environmental Risk Assessment
Chapter; U.S.
Environmental Protection Agency, Office of Prevention, Pesticides and Toxic Substances, Office of
Pesticide
Programs, Environmental Fate and Effects Division, U.S. Government Printing Office: Washington, DC,
1999.
Nitschke, K. D.; Eisenbrandt, D. L. Agents: Sulfuryl Fluoride. Handbook of Pesticide
Toxicology;
Academic Press:
San Diego, CA, 2001; p 1881.
Wexler, A. Vapor Pressure Formulation for Water in Rango 0 to 100 °C. J. Res. 1996,
80A,
775–785.
Mackay, D.; Shiu, W-Y.; Ma, K-C. Physical-Chemical Properties, Vapor Pressure. Illustrated
Handbook of
Physical-
Chemical Properties and Environmental Fate for Organic Chemicals; CRC Press LLC: Boca
Raton,
FL,
1997; p 8.
Ney, Jr., R. E. Chapter 1: Fundamentals. Fate and Transport of Organic Chemicals in the
Environment, A
Practical
Guide, 2nd ed.; Government Institutes, Inc.: Rockville, MD, 1995; pp 1–2, 18, 174, 182.
Popendorf, W. Vapor Pressure in Mixtures. Industrial Hygiene Control of Airborne Chemical
Hazards;
Taylor and
Francis Group: Boca Raton, FL, 2006; pp 141-171.
Dorn, E.; Hansen, P.; Ogg, C.; Bauer, E.; Hygnstrom, J. 5 Things to Know to Avoid Herbicide
Drift;
CropWatch,
University of Nebraska–Lincoln Extension: Lincoln, NE, 2014.
PRN 2001-X Draft: Spray and Dust Drift Label Statements for Pesticide Products; U.S.
Environmental
Protection
Agency, Office of Prevention, Pesticides and Toxic Substances, Office of Pesticide Programs,
Environmental
Fate and Effects Division, U.S. Government Printing Office: Washington, DC, 2001.
Fishel, F. M. ; Ferrell, J. A. Managing Pesticide Drift; University of Florida Extension:
Gainesville, FL, 2013.
NPIC fact sheets are designed to answer questions
that
are
commonly
asked by the general public about pesticides that are regulated by the
U.S. Environmental Protection Agency (US EPA). This document is
intended to be educational in nature and helpful to consumers for
making decisions about pesticide use.